The Phosphate Adsorption Isotherms in a New Tidal Rice Field of Barito Kuala Regency South Kalimantan

Fadly Hairannoor Yusran; Zuraida Titin Mariana; Windi Bunga Devita

doi:10.5400/jts.2025.v1i1.%p

The Phosphate Adsorption Isotherms in a New Tidal Rice Field of Barito Kuala Regency South Kalimantan

Fadly Hairannoor Yusran, Zuraida Titin Mariana, Windi Bunga Devita

Abstract

Acid sulphate soils are sub-optimum lands with many chemical problems. The research aimed to examine the characteristics of P adsorption and solubility using the adsorption isotherm equation. This research was an incubation study using soil samples from Ray 7, Balandean Village, Alalak District, Barito Kuala Regency, South Kalimantan Province from May to November 2022. The adsorption isotherm of P was measured in six soil samples with three replicates. Added P (0, 2, 5, 10, 15, 30, and 50 mg P kg-1) from KH2PO4 were applied in 1 g soil in 25 mL 0.01 M CaCl2. The suspensions were shaken in at 25 ℃ for 17 hours, then centrifuged at 3000 rpm for five minutes and the supernatant was filtered for P analysis. Three common adsorption isotherm equations, Langmuir, Freundlich, and Brunauer-Emmett- Teller (BET) were used to fit the data. The high solubility of Al and Fe was thought to influence the adsorption of P as well as the reduction state of soil components were believed to change the properties of the soil in adsorbing P nutrients, even though they came from the same parent rocks. The BET equation was more suitable for describing P adsorption isotherm in this type of soil.

Keywords

Adsorption isotherm, P solubility, acid sulfate soil, C, Al, and Fe metals.

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DOI: http://dx.doi.org/10.5400/jts.2025.v1i1.%25p